The Animation Paper – Pre Release is now available. Currently in Alpha but check it out, download it and give feedback
MocapX is a Facial motion capture app for the iPhone that streams the mocap data to Maya in real-time
Advanced Skeleton has been used to rig creatures, props, vehicles and just about anything since 1999. It is free to download but if you want to use it for a commercial project you will have to buy a license.
The Setup Machine enables Maya users to easily and quickly rig a wide variety of CG characters with just a few clicks. Generate a flexible, modern character rig in minutes saving you days or weeks of work
Rough Animator is a fully featured hand drawn animation application that runs on Android, iOS, Mac OS, and Windows. Currently available for $4.99
Storyboarder is a free open-source piece of storyboarding software that makes it easy to visualize a story as fast you can draw stick figures.