The Animation Paper – Pre Release is now available. Currently in Alpha but check it out, download it and give feedback
MocapX is a Facial motion capture app for the iPhone that streams the mocap data to Maya in real-time
Advanced Skeleton has been used to rig creatures, props, vehicles and just about anything since 1999. It is free to download but if you want to use it for a commercial project you will have to buy a license.
Storyboarder is a free open-source piece of storyboarding software that makes it easy to visualize a story as fast you can draw stick figures.
Krita is a free app for digital painting but also supports 2D animation. It is made by artists that want to see affordable art tools for everyone.
Live2D has a bunch of software that allows 2D artists to create animations from their artwork. Available in both FREE and PRO versions.
MakeHuman is a free open-source software that allows you to create and pose 3D human characters. Useful for pose reference.